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Okay, It was the Hittites that discovered Iron Smelting. Here is a smorgasbord of sources:Hittites: The People That Discovered the Iron, HISTORY OF THE HITTITES , The Hittites and the Dawn of the Iron Age. I just wanted to close out my argument.
Here is a slideshow from Newsweek which shows some pretty significant inventions:Innovations That Rocked the World
